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Low-spin Bis(2-methylimidazole)(octaethylporphyrinato)iron(III) Chloride (perp-[Fe(OEP)(2-MeHIm)(2)]Cl). A Consequence of Hydrogen Bonding?
The synthesis and characterization of low-spin bis(2-methylimidazole)(octaethylporphyrinato)iron(III) chloride (perp-[Fe(OEP)(2-MeHIm)(2)]Cl) is reported. The structure shows that the cation is a low-spin species with two imidazole ligands having a relative perpendicular orientation. The porphyrin c...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1931517/ https://ncbi.nlm.nih.gov/pubmed/17112268 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic061014u |
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