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A cationic host displaying positive cooperativity in water
The affinity of guanidinium and Cu(II) containing hosts for polycarboxylate guests is studied in water by using UV-visible spectroscopy and isothermal titration calorimetry. By combining a Cu(II) coordination site and a diguanidinium moiety around a single scaffold it is found that the Gibbs free-en...
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Main Authors: | , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
National Academy of Sciences
2007
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1871821/ https://ncbi.nlm.nih.gov/pubmed/17420472 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609144104 |
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