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A cationic host displaying positive cooperativity in water

The affinity of guanidinium and Cu(II) containing hosts for polycarboxylate guests is studied in water by using UV-visible spectroscopy and isothermal titration calorimetry. By combining a Cu(II) coordination site and a diguanidinium moiety around a single scaffold it is found that the Gibbs free-en...

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Detalhes bibliográficos
Main Authors: Hughes, Andrew D., Anslyn, Eric V.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1871821/
https://ncbi.nlm.nih.gov/pubmed/17420472
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609144104
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