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Metallophosphite-Catalyzed Asymmetric Acylation of α,β -Unsaturated Amides
The l-menthone-derived TADDOL phosphite 6b catalyzes highly enantioselective conjugate additions of acyl silanes to α,β-unsaturated amides. p-Methoxybenzoyl cyclohexyldimethylsilane adds to a variety of N,N-dimethyl acrylamide derivatives in the presence of the lithium salt of 6b. In many instances...
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2006
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1868422/ https://ncbi.nlm.nih.gov/pubmed/16492064 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja056018x |
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