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Metallophosphite-Catalyzed Asymmetric Acylation of α,β -Unsaturated Amides
The l-menthone-derived TADDOL phosphite 6b catalyzes highly enantioselective conjugate additions of acyl silanes to α,β-unsaturated amides. p-Methoxybenzoyl cyclohexyldimethylsilane adds to a variety of N,N-dimethyl acrylamide derivatives in the presence of the lithium salt of 6b. In many instances...
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| Главные авторы: | , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2006
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1868422/ https://ncbi.nlm.nih.gov/pubmed/16492064 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja056018x |
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