C–C σ complexes of rhodium

In this article, the complexes [Rh(Binor-S′)(PR(3))][BAr(4)(F)] (R = (i)Pr, Cy, C(5)H(9)) are described. A combination of x-ray crystallography, NMR spectroscopy, density functional theory, and “atoms in molecules” calculations unequivocally demonstrates that the complexes contain rare examples of m...

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Détails bibliographiques
Auteurs principaux: Brayshaw, Simon K., Sceats, Emma L., Green, Jennifer C., Weller, Andrew S.
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2007
Sujets:
Coordination Chemistry of Saturated Molecules Special Feature
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC1855424/
https://ncbi.nlm.nih.gov/pubmed/17435164
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609824104
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