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The activation of alkyl cyanides using a rhodiumtrispyrazolylborate complex
The photochemical reaction of Tp′Rh(L)(η(2)-PhN=L) [Tp′ = tris-(3,5-dimethyl pyrazolyl)borate, L = CNCH(2)CMe(3)] to form the coordinatively unsaturated reactive fragment, [Tp′Rh(L)], in the presence of alkylnitriles has been studied. The [Tp′Rh(L)] complex has been shown to selectively activate the...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1855398/ https://ncbi.nlm.nih.gov/pubmed/17384154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0609726104 |
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