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Palladium-catalyzed cross-coupling reaction of alkenyl bromides with potassium alkyltrifluoroborates
The Suzuki-Miyaura-type cross-coupling reaction of potassium alkyltrifluoroborates with various alkenyl bromides in the presence of 10 mol % of PdCl(2)(dppf)·CH(2)Cl(2) and 3.0 equiv of Cs(2)CO(3) in aqueous toluene at 80 °C provided the desired compounds in 49–95% yields. A variety of functional gr...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1827200/ https://ncbi.nlm.nih.gov/pubmed/18196177 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2006.10.088 |
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