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Mirror-Image Carbohydrates: Synthesis of the Unnatural Enantiomer of a Blood Group Trisaccharide
Methyl d-glucoside and d-glucose pentaacetate are transformed, respectively, into methyl α-O-glucuronide 3 and hydroxymethyl β-C-glucuronide 9, which undergo decarboxylative elimination efficiently to produce 4-deoxypentenoside 4 and l-glucal 10. These unsaturated pyranosides provide an expeditious...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2004
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1820887/ https://ncbi.nlm.nih.gov/pubmed/15132547 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo035789l |
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