Mechanism of metal-independent decomposition of organic hydroperoxides and formation of alkoxyl radicals by halogenated quinones

The metal-independent decomposition of organic hydroperoxides and the formation of organic alkoxyl radicals in the absence or presence of halogenated quinones were studied with electron spin resonance (ESR) and the spin-trapping agent 5,5-dimethyl-1-pyrroline N-oxide (DMPO). We found that 2,5-dichlo...

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Main Authors: Zhu, Ben-Zhan, Zhao, Hong-Tao, Kalyanaraman, Balaraman, Liu, Jun, Shan, Guo-Qiang, Du, Yu-Guo, Frei, Balz
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2007
Teme:
Physical Sciences
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC1820646/
https://ncbi.nlm.nih.gov/pubmed/17360415
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0605527104
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