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A highly enantio- and diastereoselective 1,3-dimethylallylation of aldehydes
A highly enantio- and diastereoselective pentenylation of aldehydes is described. The homoallylic alcohol derived from 1,3-dimethylallylation of (−)-menthone undergoes an efficient allyl-transfer reaction with a wide range of aliphatic aldehydes in the presence of an acid catalyst to give rise to th...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1761486/ https://ncbi.nlm.nih.gov/pubmed/17203133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2006.07.070 |
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