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A Trojan horse transition state analogue generated by MgF(3)(−) formation in an enzyme active site
Identifying how enzymes stabilize high-energy species along the reaction pathway is central to explaining their enormous rate acceleration. β-Phosphoglucomutase catalyses the isomerization of β-glucose-1-phosphate to β-glucose-6-phosphate and appeared to be unique in its ability to stabilize a high-...
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| Main Authors: | , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1595420/ https://ncbi.nlm.nih.gov/pubmed/16990434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0604448103 |
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