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Electronic Configuration Assignment and the Importance of Low-Lying Excited States in High-Spin Imidazole-Ligated Iron(II) Porphyrinates
The synthesis and characterization of six new high-spin deoxymyoglobin models (imidazole(tetraarylporphyrinato)iron(II)) are described. These have been intensively studied by temperature-dependent Mössbauer spectroscopy from 295 to 4.2 K. All complexes show a strong temperature dependence for the qu...
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| Hauptverfasser: | , , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2005
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1552104/ https://ncbi.nlm.nih.gov/pubmed/15826208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja044077p |
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