The organometallic active site of [Fe]hydrogenase: Models and entatic states

The simple organometallic, (μ-S(2))Fe(2)(CO)(6), serves as a precursor to synthetic analogues of the chemically rudimentary iron-only hydrogenase enzyme active site. The fundamental properties of the (μ-SCH(2)CH(2)CH(2)S)[Fe(CO)(3)](2) compound, including structural mobility and regioselectivity in...

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Hauptverfasser: Darensbourg, Marcetta Y., Lyon, Erica J., Zhao, Xuan, Georgakaki, Irene P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: The National Academy of Sciences 2003
Schlagworte:
Physical Sciences
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC152982/
https://ncbi.nlm.nih.gov/pubmed/12642671
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0536955100
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