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Electronic structure of polyenes related to the visual chromophore. A simple model for the observed band shapes.
A model is presented which attributes the widths of absorption bands in carotenoids to conformational disorder induced by the beta-ionylidene moiety. With reasonable parameter choices, the model gives a good quantitative fit to the spectra observed for four carotenoids and at the same time accounts...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
1977
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1473364/ https://ncbi.nlm.nih.gov/pubmed/922126 |
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