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Electronic structure of polyenes related to the visual chromophore. A simple model for the observed band shapes.

A model is presented which attributes the widths of absorption bands in carotenoids to conformational disorder induced by the beta-ionylidene moiety. With reasonable parameter choices, the model gives a good quantitative fit to the spectra observed for four carotenoids and at the same time accounts...

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Detalhes bibliográficos
Main Authors: Hemley, R, Kohler, B E
Formato: Artigo
Idioma:Inglês
Publicado em: 1977
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1473364/
https://ncbi.nlm.nih.gov/pubmed/922126
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