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Stereoselective Synthesis of α,α′-Biprolines

[Figure: see text] A means to induce dehydrodimerization of Seebach’s oxazolidinone (5), the stereochemical outcome of which is entirely temperature dependent, is described. The resultant dimers 3 and 4 are precursors to (R,R)-α,α′-biproline (1) and meso-α,α′-biproline (2), respectively. An organohy...

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Detalhes bibliográficos
Main Authors: Vartak, Ashish P., Young, Victor G., Johnson, Rodney L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1388272/
https://ncbi.nlm.nih.gov/pubmed/15624971
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol047958
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