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Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes
The bis(cyclopentadienyl)(tert-butylimido)zir-conium complex 1 undergoes ambient-temperature metathesis reactions with nitro- and nitrosoarenes, providing a rare nonphotochemical synthesis of cis-azoxy and cis-azo compounds, respectively. 2-Nitro-2-methylpropane also undergoes metathesis to give tra...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2004
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1383656/ https://ncbi.nlm.nih.gov/pubmed/16508695 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0495776 |
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