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Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido Complexes

[Image: see text] Several tantalum imido complexes have been synthesized and shown to efficiently catalyze the hydroamination of internal and terminal alkynes. An unusual hydroamination/hydroarylation reaction of norbornene catalyzed by a highly electrophilic cationic tantalum imido complex is also...

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Main Authors: Anderson, Laura L., Arnold, John, Bergman, Robert G.
格式: Artigo
語言:Inglês
出版: 2004
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC1325215/
https://ncbi.nlm.nih.gov/pubmed/15255680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0492851
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