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Energetics of nanocrystalline TiO(2)

The energetics of the TiO(2) polymorphs (rutile, anatase, and brookite) were studied by high temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is 0.71 ± 0.38 kJ/mol (6) and bulk anatase is 2.61 ± 0.41 kJ/mol higher in enthalpy. The surface enthalpies of rutile,...

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Publicat a:Proc Natl Acad Sci U S A
Autors principals: Ranade, M. R., Navrotsky, A., Zhang, H. Z., Banfield, J. F., Elder, S. H., Zaban, A., Borse, P. H., Kulkarni, S. K., Doran, G. S., Whitfield, H. J.
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2002
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Accés en línia:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC128553/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/11880610/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.251534898
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