Energetics of nanocrystalline TiO(2)

The energetics of the TiO(2) polymorphs (rutile, anatase, and brookite) were studied by high temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is 0.71 ± 0.38 kJ/mol (6) and bulk anatase is 2.61 ± 0.41 kJ/mol higher in enthalpy. The surface enthalpies of rutile,...

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Bibliographic Details
Main Authors: Ranade, M. R., Navrotsky, A., Zhang, H. Z., Banfield, J. F., Elder, S. H., Zaban, A., Borse, P. H., Kulkarni, S. K., Doran, G. S., Whitfield, H. J.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2002
Subjects:
Colloquium
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC128553/
https://ncbi.nlm.nih.gov/pubmed/11880610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.251534898
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