Energetics of nanocrystalline TiO(2)

The energetics of the TiO(2) polymorphs (rutile, anatase, and brookite) were studied by high temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is 0.71 ± 0.38 kJ/mol (6) and bulk anatase is 2.61 ± 0.41 kJ/mol higher in enthalpy. The surface enthalpies of rutile,...

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Bibliographische Detailangaben
Hauptverfasser: Ranade, M. R., Navrotsky, A., Zhang, H. Z., Banfield, J. F., Elder, S. H., Zaban, A., Borse, P. H., Kulkarni, S. K., Doran, G. S., Whitfield, H. J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2002
Schlagworte:
Colloquium
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC128553/
https://ncbi.nlm.nih.gov/pubmed/11880610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.251534898
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