Energetics of nanocrystalline TiO(2)

The energetics of the TiO(2) polymorphs (rutile, anatase, and brookite) were studied by high temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is 0.71 ± 0.38 kJ/mol (6) and bulk anatase is 2.61 ± 0.41 kJ/mol higher in enthalpy. The surface enthalpies of rutile,...

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Autores principales: Ranade, M. R., Navrotsky, A., Zhang, H. Z., Banfield, J. F., Elder, S. H., Zaban, A., Borse, P. H., Kulkarni, S. K., Doran, G. S., Whitfield, H. J.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2002
Materias:
Colloquium
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC128553/
https://ncbi.nlm.nih.gov/pubmed/11880610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.251534898
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