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Chiral protein scissors: High enantiomeric selectivity for binding and its effect on protein photocleavage efficiency and specificity
Chiral recognition of protein-binding sites by a simple organic molecule with selectivities >100 is reported here. The l-isomer of 4(1-pyrene)-3-butyroyl-phenylalanine amide (Py-l-Phe) binds to BSA with an affinity constant (K(b)) of 3 × 10(7) M(−1), whereas the corresponding d-isomer (Py-d-Phe)...
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| Päätekijät: | , , , , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
The National Academy of Sciences
2002
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC122858/ https://ncbi.nlm.nih.gov/pubmed/11972031 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.082119599 |
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