Configurationally homogeneous diastereomers of a linear hexa(tertiary phosphine): Enantioselective self-assembly of a double-stranded parallel helicate of the type (P)-[Cu(3)(hexaphos)(2)](PF(6))(3)

Three configurationally homogeneous diastereomers of the linear hexa(tertiary phosphine) Ph(2)PCH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)P(Ph)CH(2)CH(2)PPh(2) (hexaphos) have been isolated in enantiomerically pure form, namely (R,S,S,R)-, (R,S,S,S)-, and (S,S,S,S)-hexaphos. The strongly...

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Detalhes bibliográficos
Main Authors: Bowyer, Paul K., Cook, Vernon C., Gharib-Naseri, Nahid, Gugger, Paul A., Rae, A. David, Swiegers, Gerhard F., Willis, Anthony C., Zank, Johann, Wild, S. Bruce
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2002
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC122687/
https://ncbi.nlm.nih.gov/pubmed/11929976
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.072640699
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