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Derivation of molecular pK values from pH-dependences.
If the titration pK values of a dibasic acid are called pK +/- logp, then its molecular pK values are pK +/- log(p+1/p). If the pH values at which the concentration of its monoprotonated form is half-maximal are called pK +/- logq, then its molecular pK values are pK +/- log(q-4+1/q).
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
1979
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1186362/ https://ncbi.nlm.nih.gov/pubmed/34389 |
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