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Reaction coordinates and rates from transition paths

The molecular mechanism of a reaction in solution is reflected in its transition-state ensemble and transition paths. We use a Bayesian formula relating the equilibrium and transition-path ensembles to identify transition states, rank reaction coordinates, and estimate rate coefficients. We also int...

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Hlavní autoři: Best, Robert B., Hummer, Gerhard
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2005
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC1100744/
https://ncbi.nlm.nih.gov/pubmed/15814618
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0408098102
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