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The question of C- vs. O-silylation of ketenes: Electrophilic triethylsilylation of diphenylketene
Electrophilic triethylsilylation of diphenylketene leads to exclusive C-silylation giving the diphenyl(triethylsilyl)acetyl cation in the solution phase even though density functional theory calculations at the B3LYP/6-311+G(*) level indicate that the O-silylation of diphenylketene is preferred over...
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| Hoofdauteurs: | , , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
National Academy of Sciences
2005
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1088379/ https://ncbi.nlm.nih.gov/pubmed/15840718 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0501813102 |
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