Synthesis and Properties of Octithiophene Dication Sterically Segregated by Annelation with Bicyclo[2.2.2]octene Units

Octithiophene sterically segregated by annelation with bicyclo[2.2.2]octene (BCO) units was synthesized to study the unimolecular properties of longer oligothiophene dications. For the preparation of such longer oligomers, a new route for the synthesis of the monomer annelated with BCO unit at the 3...

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Principais autores: Koichi Komatsu, Masahiko Iyoda, Masaki Tateno, Tohru Nishinaga, Daisuke Yamazaki
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2010-03-01
coleção:Materials
Assuntos:
bipolaron
dication
oligothiophene
polaron pair
singlet biradical
Acesso em linha:http://www.mdpi.com/1996-1944/3/3/2037/
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