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Spin Cross-Over (SCO) Anionic Fe(II) Complexes Based on the Tripodal Ligand Tris(2-pyridyl)ethoxymethane

Reactions of Fe(II) with the tripodal chelating ligand 1,1,1-tris(2-pyridyl)ethoxymethane (py<sub>3</sub>C-OEt) and (NCE)<sup>−</sup> co-ligands (E = S, Se, BH<sub>3</sub>) give a series of mononuclear complexes formulated as [Fe(py<sub>3</sub>C-OEt)<sub>2</sub>][Fe(py<sub>3</sub>C-OEt)(NCE)<sub>3</...

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Principais autores: Emmelyne Cuza, Samia Benmansour, Nathalie Cosquer, Françoise Conan, Sébastien Pillet, Carlos J. Gómez-García, Smail Triki
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2020-06-01
Serier:Magnetochemistry
Fag:
tripodal ligands
iron complex
spin cross-over
infrared spectroscopy
magnetic properties
Online adgang:https://www.mdpi.com/2312-7481/6/2/26
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