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The Relationship Between Spin Crossover (SCO) Behaviors, Cation and Ligand Motions, and Intermolecular Interactions in a Series of Anionic SCO Fe(III) Complexes with Halogen-Substituted Azobisphenolate Ligands

To investigate the halogen substitution effect on the anionic spin crossover (SCO) complexes, azobisphenolate ligands with 5,5′-dihalogen substituents from fluorine to iodine were synthesized, and their anionic Fe<sup>III</sup> complexes <b>1F</b>, <b>1Cl</b>, <b>1Br</b>, and <b>1I</b> were isolated...

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Principais autores: Mai Hirota, Suguru Murata, Takahiro Sakurai, Hitoshi Ohta, Kazuyuki Takahashi
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2024-11-01
coleção:Molecules
Assuntos:
spin crossover
Fe(III) complex
anionic complex
2,2′-azobisphenolate ligand
halogen substituent effect
cooperativity
Acesso em linha:https://www.mdpi.com/1420-3049/29/22/5473
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