Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases

The behaviour of triazolylidene ligands coordinated at a {Fe₂(CO)₅(µ-dithiolate)} core related to the active site of [FeFe]-hydrogenases have been considered to determine whether such carbenes may act as redox electron-reservoirs, with innocent or non-innocent properties. A nov...

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Hauptverfasser:	Andrea Mele, Federica Arrigoni, Catherine Elleouet, François Y. Pétillon, Philippe Schollhammer, Giuseppe Zampella
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	MDPI AG 2022-07-01
Schriftenreihe:	Molecules
Schlagworte:	non-innocent ligand redox ligand mesoionic carbene triazolylidene DFT calculations di-iron complexes
Online-Zugang:	https://www.mdpi.com/1420-3049/27/15/4700
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