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Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases

The di-iron carbonyl dithiolene bridged complex [Fe<sub>2</sub>(CO)<sub>6</sub>(<i>µ</i>-S<sub>2</sub>C<sub>2</sub>(CO<sub>2</sub>Me)<sub>2</sub>)] (<b>1</b>) reacts with 1 equivalent of phosphane PR<sub>3</sub> (R = Ph, OMe) to give, as major products, monosubstituted derivatives [Fe<sub>2</sub>(CO...

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Principais autores: Mohamed Kdider, Catherine Elleouet, François Y. Pétillon, Philippe Schollhammer
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2023-09-01
Serier:Molbank
Fag:
dinuclear complexes
iron
dithiolene bridge
carbonyl
phosphane
metal–sulfur
Online adgang:https://www.mdpi.com/1422-8599/2023/3/M1719
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