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Charge Dependent Capacitance of Stern Layer and Capacitance of Electrode/Electrolyte Interface

The influence of potential dependent relative permittivity of Stern layer on the capacitance of electrode-electrolyte interface is studied theoretically. A decrease of capacitance at larger magnitudes of electrode surface potential is predicted. At large electrode surface potentials the capacitance...

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Principais autores: Aljaž Velikonja, Ekaterina Gongadze, Veronika Kralj-Iglič, Aleš Iglič
Format: Artigo
Sprog:Inglês
Udgivet: Elsevier 2014-11-01
Serier:International Journal of Electrochemical Science
Fag:
capacitance
electric double layer
Stern layer
relative permittivity
water ordering
Online adgang:http://www.sciencedirect.com/science/article/pii/S145239812310856X
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