Charge Dependent Capacitance of Stern Layer and Capacitance of Electrode/Electrolyte Interface

The influence of potential dependent relative permittivity of Stern layer on the capacitance of electrode-electrolyte interface is studied theoretically. A decrease of capacitance at larger magnitudes of electrode surface potential is predicted. At large electrode surface potentials the capacitance...

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Autors principals:	Aljaž Velikonja, Ekaterina Gongadze, Veronika Kralj-Iglič, Aleš Iglič
Format:	Artigo
Idioma:	Inglês
Publicat:	Elsevier 2014-11-01
Col·lecció:	International Journal of Electrochemical Science
Matèries:	capacitance electric double layer Stern layer relative permittivity water ordering
Accés en línia:	http://www.sciencedirect.com/science/article/pii/S145239812310856X
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