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Electrochemical and Spectroscopic Investigation of Bioactive Naphthoquinones

The present work aims to investigate the electrochemical behavior of nine naphthoquinones, in aprotic and protic media. The reduction mechanism of the quinones in aprotic medium was proposed, with involvement of anion radical species, confirmed by performing in-situ Electrochemical-Electron Spin Res...

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Principais autores: Erivaldo de Oliveira Costa, María Teresa Molina, Fabiane Caxico de Abreu, Francisco de Assis dos Santos Silva, Cicero de Oliveira Costa, Waldomiro Pinho, Jr, Iara B. Valentim, Benjamín Aguilera-Venegas, Fernanda Pérez-Cruz, Ester Norambuena, Claudio Olea-Azar, Marília O.F. Goulart
Format: Artigo
Sprog:Inglês
Udgivet: Elsevier 2012-01-01
Serier:International Journal of Electrochemical Science
Fag:
naphthoquinones
radical dianion;
ESR
electrochemical reduction
self-protonation
Online adgang:http://www.sciencedirect.com/science/article/pii/S1452398123195009
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