Triflamidation of Allyl-Containing Substances:Unusual Dehydrobromination vs. Intramolecular Heterocyclization

Allyl halides with triflamide under oxidative conditions form halogen-substituted amidines. Allyl cyanide reacts with triflamide in acetonitrile or THF solutions in the presence of NBS to give the products of bromotriflamidation with a solvent interception, whereas in CH₂Cl₂ tw...

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Bibliografiset tiedot

Päätekijät:	Anton S. Ganin, Mikhail Yu. Moskalik, Ivan A. Garagan, Vera V. Astakhova, Bagrat A. Shainyan
Aineistotyyppi:	Artigo
Kieli:	Inglês
Julkaistu:	MDPI AG 2022-10-01
Sarja:	Molecules
Aiheet:	allyl cyanide allyl halides triflamide oxidative bromotriflamidation solvent interception heterocyclization
Linkit:	https://www.mdpi.com/1420-3049/27/20/6910
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