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Stacked antiaromatic porphyrins

It has been proposed that stacking antiaromatic molecules can build three-dimensional aromaticity, but this claim has lacked experimental validation. Here the authors report that π–π stacked antiaromatic porphyrins display significantly reduced antiaromaticity in solid state and in solution.

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Bibliografski detalji
Glavni autori: Ryo Nozawa, Hiroko Tanaka, Won-Young Cha, Yongseok Hong, Ichiro Hisaki, Soji Shimizu, Ji-Young Shin, Tim Kowalczyk, Stephan Irle, Dongho Kim, Hiroshi Shinokubo
Format: Artigo
Jezik:Inglês
Izdano: Nature Portfolio 2016-11-01
Serija:Nature Communications
Online pristup:https://doi.org/10.1038/ncomms13620
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