Highly Electron‐Donating Antiaromatic N,N′‐Dimethyldiazaporphyrins via Reductive Dimethylation
Ni(II) N,N′‐dimethyl‐5,15‐diazaporhyrins are efficiently prepared through reductive dimethylation of 5,15‐diazaporphyrin Ni(II) complexes with sodium dispersion in the presence of dimethyl sulfate. The obtained reduced diazaporphyrins exhibit highly upfield‐shifted 1H NMR spectra and narrowed HOMO–L...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Wiley-VCH
2025-09-01
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| Series: | ChemistryEurope |
| Assuntos: | |
| Acceso en liña: | https://doi.org/10.1002/ceur.202500109 |
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