Use of the Asymmetrical Chelating N-Donor 2-Imino-Pyridine as a Redox [Fe4S4] Cubane Surrogate at a Di-Iron Site Related to [FeFe]-Hydrogenases
Two complexes, related to the active site of [FeFe]-hydrogenases, [Fe<sub>2</sub>(CO)<sub>4</sub>(<i>κ</i><sup>2</sup>-pma)(<i>µ</i>-bdt)] (<b>1</b>) and [Fe<sub>2</sub>(CO)<sub>4</sub>(<i>κ</i><sup>2</sup>-pma)(<i>µ</i>-pdt)] (<b>2</b>) (bdt = benzene-1,2-dithiolate, pdt = propane-1,2-dithiolate) f...
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| Autori principali: | , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
MDPI AG
2023-11-01
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| Serie: | Inorganics |
| Soggetti: | |
| Accesso online: | https://www.mdpi.com/2304-6740/11/12/463 |
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