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A new convenient method for preparing tetrabutylammonium closo-dodecaborate

A new synthetic procedure for preparing tetrabutylammonium closo-dodecaborate (Bu4N)2B12H12 by the solvent-free pyrolysis of tetrabutylammonium tetrahydroborate Bu4NBH4 has been developed. The procedure also provides isolation of pure tetrabutylammonium octahydrotriborate Bu4NB3H8 as a by-product. T...

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Autors principals: Artem M. Mishchenko, Maxim A. Nechayev, Andrii I. Subota, Andriy V. Kozytskiy, Oleh V. Svaliavyn, Yulian L. Lishchenko, Anastasiia M. Aleksandrova, Yuliya V. Rassukana, Dmytro O. Leha
Format: Artigo
Idioma:Inglês
Publicat: National University of Pharmacy (Kharkiv) 2024-12-01
Col·lecció:Журнал органічної та фармацевтичної хімії
Matèries:
closo-dodecaborate
octahydrotriborate
pyrolysis
dft calculations
Accés en línia:https://ophcj.nuph.edu.ua/article/view/316264
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