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Facile Attachment of Halides and Pseudohalides to Dodecaborate(2-) via Pd-catalyzed Cross-Coupling

Cross-coupling reactions with [B<sub>12</sub>H<sub>11</sub>I]<sup>2−</sup> as one partner have been used successfully for Kumada and Buchwald Hartwig couplings with Pd catalysis. Here, we found that the iodide could be substituted easily, and unexpectedly, with other halides such as Br and Cl, and w...

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Principais autores: Mahmoud K. Al-Joumhawy, Jui-Chi Chang, Fariba Sabzi, Detlef Gabel
Formato: Artigo
Idioma:Inglês
Publicado: MDPI AG 2023-04-01
Series:Molecules
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Acceso en liña:https://www.mdpi.com/1420-3049/28/7/3245
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