Pivotal Synthesis of Tetrasubstituted Epoxides from Ketones and α‐Halo B/Si Ylides with Understanding of the Activation Modes

The epoxidation of ketones with α‐monohalo borylsilylmethane reagents renders tetrasubstituted epoxides, opening a new reactive pathway by supression of Boron‐Wittig or Peterson olefination pathways. This method enables the preparation of novel 1,1,2,2‐tetrasubstituted borosilylepoxides with intrins...

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Principais autores:	Luis Tarifa, Edmond Apaloo‐Messan, Paula Dominguez‐Molano, Lucia Morán‐González, Oriol Salvadó, Stanley Wilkinson, Marcos Rodríguez, Feliu Maseras, Elena Fernández
格式:	Artigo
語言:	Inglês
出版:	Wiley-VCH 2026-01-01
叢編:	ChemistryEurope
主題:	boron ylides density functional theory calculations epoxidation mechanisms stereoselectivity
在線閱讀:	https://doi.org/10.1002/ceur.202500241
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