Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration

Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy fo...

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Hlavní autoři:	Ming Hou, Yuanrui Wang, Hefei Yang, Jiajun Zhang, Prof. Dr. Xiao‐Feng Wu
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Wiley-VCH 2025-05-01
Edice:	ChemistryEurope
Témata:	nitrogen-centered radical photocatalysis unactivated alkenes carbonylation amination
On-line přístup:	https://doi.org/10.1002/ceur.202500001
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