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Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration

Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy fo...

Ausführliche Beschreibung

Gespeichert in:
Hauptverfasser: Ming Hou, Yuanrui Wang, Hefei Yang, Jiajun Zhang, Prof. Dr. Xiao‐Feng Wu
Format: Artigo
Sprache:Inglês
Veröffentlicht: Wiley-VCH 2025-05-01
Schriftenreihe:ChemistryEurope
Schlagworte:
nitrogen-centered radical
photocatalysis
unactivated alkenes
carbonylation
amination
Online-Zugang:https://doi.org/10.1002/ceur.202500001
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