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Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

Isocyanoazulenes (CNAz) constitute a relatively new class of isocyanoarenes that offers rich structural and electronic diversification of the organic isocyanide ligand platform. This article considers a series of 2-isocyano-1,3-X<sub>2</sub>-azulene ligands (X = H, Me, CO<sub>2</sub>Et, Br, and CN)...

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Principais autores: Mason D. Hart, John J. Meyers, Zachary A. Wood, Toshinori Nakakita, Jason C. Applegate, Nathan R. Erickson, Nikolay N. Gerasimchuk, Mikhail V. Barybin
Formato: Artigo
Idioma:Inglês
Publicado: MDPI AG 2021-02-01
Series:Molecules
Assuntos:
chromium pentacarbonyl
isocyanide
azulene
back-bonding
metal-to-ligand charge transfer
voltammetry
Acceso en liña:https://www.mdpi.com/1420-3049/26/4/981
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