Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

Isocyanoazulenes (CNAz) constitute a relatively new class of isocyanoarenes that offers rich structural and electronic diversification of the organic isocyanide ligand platform. This article considers a series of 2-isocyano-1,3-X₂-azulene ligands (X = H, Me, CO₂Et, Br, and CN)...

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Detalhes bibliográficos

Principais autores:	Mason D. Hart, John J. Meyers, Zachary A. Wood, Toshinori Nakakita, Jason C. Applegate, Nathan R. Erickson, Nikolay N. Gerasimchuk, Mikhail V. Barybin
Formato:	Artigo
Idioma:	Inglês
Publicado em:	MDPI AG 2021-02-01
coleção:	Molecules
Assuntos:	chromium pentacarbonyl isocyanide azulene back-bonding metal-to-ligand charge transfer voltammetry
Acesso em linha:	https://www.mdpi.com/1420-3049/26/4/981
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