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Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides

The widespread use of biaryl monophosphines is frequently hampered by the challenges associated with their modular preparation. Here, the authors report a protocol that appends arenes to arylphosphines to access a series of these compounds via rhodium-catalysed P(III)- directed ortho C–H activation,...

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Principais autores: Dingyi Wang, Mingjie Li, Chengdong Shuang, Yong Liang, Yue Zhao, Minyan Wang, Zhuangzhi Shi
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Portfolio 2022-05-01
coleção:Nature Communications
Acesso em linha:https://doi.org/10.1038/s41467-022-30697-7
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