Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides

A co-catalyst of (PPh3)AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity.

Bibliografiske detaljer

Principais autores:	Chen Zhang, Shao-Qiao Zhang, Hua-Jun Cai, Dong-Mei Cui
Format:	Artigo
Sprog:	Inglês
Udgivet:	Beilstein-Institut 2013-05-01
Serier:	Beilstein Journal of Organic Chemistry
Fag:	allene gold catalysis hydroamination N-sulfonyl selectivity sulfonamide
Online adgang:	https://doi.org/10.3762/bjoc.9.117
Tags:	Tilføj Tag Ingen Tags, Vær først til at tagge denne postø!