Protecting-group-free ortho-C–H borylation of anilines enabled by mesoionic carbene-Ir complex
We describe an iridium-catalyzed ortho-selective C–H borylation of unprotected anilines. The employing strong σ-donating cyclometalated mesoionic carbene as C^C bidentate ligand is crucial for the high ortho-selectivity. Computational studies support outer-sphere X–H···Oboryl hydrogen bond interacti...
Na minha lista:
| Principais autores: | , , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
KeAi Communications Co. Ltd.
2023-11-01
|
| Colecção: | Green Synthesis and Catalysis |
| Assuntos: | |
| Acesso em linha: | http://www.sciencedirect.com/science/article/pii/S266655492200045X |
| Tags: |
Sem tags, seja o primeiro a adicionar uma tag!
|