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A novel route to 3-hydroxy-16,17-seco-estrone derivatives (NOTE)

Starting from 3-benzyloxy-17-hydroxy-16,17-secoestra-1,3,5(10)-triene-16-nitrile (1b), 17-tosylate 2b and also 17-chloro-, 17-bromo- and 17-iodo-derivatives 4b, 5b, and 6b, were obtained. The fluoro-derivative 3b was obtained from 2b in the reaction with tetrabutyl ammonium fluoride. The deprotectio...

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Principais autores: SUZANA S. JOVANOVIC-SANTA, VJERA M. PEJANOVIC, JULIJANA A. PETROVIC
Format: Artigo
Sprog:Inglês
Udgivet: Serbian Chemical Society 1999-05-01
Serier:Journal of the Serbian Chemical Society
Fag:
3-hydroxy-16
17-seco-estrone derivatives
halogeno steroids
hydrogenolysis
Online adgang:http://www.shd.org.yu/HtDocs/SHD/Vol64/No5-Pdf/V64-no5&6-9.zip
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