Preparation and Absolute Configuration of (1,4)-(+)-3-Oxo-, (1,4)-(-)-3-Oxo- and (1,3,4)-(+)-3-Acetyloxy-5-oxo-1,8-cineole
Enantiomerically pure (1S,4S)-(-)-3-oxo-1,8-cineole (-)-2 and (1R,4R)-(+)-3-oxo-1,8-cineole (+)-2 were prepared for the first time and their absolute configurations assigned by vibrational circular dichroism (VCD) measurements. Thus, treatment of cineole 1 with chromyl acetate gave rac-2 which after...
שמור ב:
| Principais autores: | , , , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
SAGE Publishing
2009-11-01
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| סדרה: | Natural Product Communications |
| גישה מקוונת: | https://doi.org/10.1177/1934578X0900401116 |
| תגים: |
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