Preparation and Absolute Configuration of (1,4)-(+)-3-Oxo-, (1,4)-(-)-3-Oxo- and (1,3,4)-(+)-3-Acetyloxy-5-oxo-1,8-cineole

Enantiomerically pure (1S,4S)-(-)-3-oxo-1,8-cineole (-)-2 and (1R,4R)-(+)-3-oxo-1,8-cineole (+)-2 were prepared for the first time and their absolute configurations assigned by vibrational circular dichroism (VCD) measurements. Thus, treatment of cineole 1 with chromyl acetate gave rac-2 which after...

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Autores principales:	María del H. Loandos, Margarita B. Villecco, Eleuterio Burgueño-Tapia, Pedro Joseph-Nathan, César A. N. Catalán
Formato:	Artigo
Lenguaje:	Inglês
Publicado:	SAGE Publishing 2009-11-01
Colección:	Natural Product Communications
Acceso en línea:	https://doi.org/10.1177/1934578X0900401116
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