Synthesis of 3-benzyloxyl-17-maleyloxy-16, 17-secoestra- 1, 3, 5 (10)-triene-16-nitrile - Sinteza 3-benziloksi-17-maleiloksi- 16, 17-sekoestra-1, 3, 5 (10)-trien-16-nitrila

Under the conditions of Beckmann fragmentation reaction 3-benzyloxy-17(-hydroxyestra-1, 3, 5, (10)-triene-16-one oxime (2) gave the D-seco derivative 3. Sodium borohydride reduction of this compound afforded 3-benzyloxy-17-hydroxy-16, 17-secoestra-1, 3, 5 (10)-triene-16-nitrile (4). The esterificati...

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Bibliografski detalji

Glavni autori:	Jovanović-Šanta Suzana S., Gaborov Sanja L., Petrović Julijana A.
Format:	Artigo
Jezik:	Inglês
Izdano:	Matica srpska 2002-01-01
Serija:	Zbornik Matice Srpske za Prirodne Nauke
Teme:	steroids 16,17-seco-estrone derivatives synthesis Beckmann fragmentation reaction esterification hemiesters
Online pristup:	http://www.doiserbia.nb.rs/img/doi/0352-4906/2002/0352-49060201005J.pdf
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